用光学多通道分析仪系统作高分辨光谱测量的技术

通常的光多通道分析仪(OMA)存在着同时谱宽与分辨率的矛盾.本文所述方法,在不减小谱宽的前提下,可将该分析仪光谱分辨率提高1～2量级,使之可适用于高分辨率谱研究.     

R_2Fe_17_C化合物的结构与内禀磁性的研究

本文系统研究了R_2Fe_17_C(R=Y,Sm,Gd,Tb、Dy.Er) 化合物的结构与内享磁性, 井与相应的R_2Fe_17_C 化合物进行了比较.R_2Fe_17_C 的居里温度比相应氏R_2Fe_17 的居里温度增加大约200K. 本文讨论了C 原子对该化合物结构与磁性的影响, 同时, 还对Sm_2(Fe_1-xCo_x)_17C系列化合物进行了研充. 关键词：     

关于可达矩阵的求法探讨

在《离散数学》、《图论》课程中 ,用矩阵表示图时 ,涉及到一类重要的矩阵——可达矩阵 ,它是判别图中任意两点是否有通路的重要手段 ,也是求强分图的重要方法 ,但是可达矩阵的求法比较复杂 .本文针对这一问题 ,对可达矩阵的求法进行了改进 ,提出了一种简单可行的算法 .     

Efficiency Enhancement of Coaxial-Cavity Electron Cyclotron Resonance Maser by Tapering Guide Magnetic Field

A coaxial-cavity cyclotron resonance maser (CRM) oscillator with tapered guide magnetic field is proposed. It is shown that the transmission quality can be improved by tapering the guide magnetic field. Simulation indicates that the efficiency of a millimeter-wave gyrotron oscillator may be reached up to 38.7% by optimizing the tapered magnetic field.     

Synthesis and optoelectronic properties of silole‐containing polyfluorenes with binary structures

2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high M_w up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007     

纳米WO3的制备及其光解水析氧性能研究

用溶胶凝胶法,灼烧法合成了纳米级WO3,采用X-射线衍射、紫外可见漫反射光谱对WO3进行表征.在Fe3 为电子受体、溶液酸度pH为2.0情况下,研究了纳米级WO3在365nm紫外辐射下光解水析氧的光催化活性,并讨论了不同方法制备的催化剂活性差异的原因.结果表明,结晶程度越高、尺寸越小、比表面积越大的纳米级WO3具有更高的光分解水析氧活性,电子受体的浓度、溶液的酸度对析氧活性有明显的影响.     

上海光源储存环磁聚焦结构设计

上海光源是一台正在建设中的低发射度第三代同步辐射光源. 经过优化后, 储存环有两种直线节长度, 周长432m,在能量3.5GeV下束流发射度为3.9nm.rad, 直线节处的β函数和色散函数有足够的调节范围. 跟踪研究表明, 即使带上磁铁高阶场误差, 储存环仍有足够大的动力学孔径和能量接受度.     

低于13K的单级脉管制冷机性能研究

回热器是脉管制冷机的关键部件之一,其效率对脉管制冷机性能有很大影响。铅丸是常见的蓄冷材料,通常用于回热器的低温端。本文测试和分析了不同品质的国产铅丸和进口铅丸对单级G-M型脉管制冷机性能的影响。采用额定功率为6．0 kW的压缩机驱动,使用进口铅丸脉管制冷机最低制冷温度达12．9 K,这是当前单级脉管制冷机达到的最低制冷温度;40 K时的最大制冷量为57．4 W。使用国产铅丸最低制冷温度为13．6 K,40 K时的最大制冷量为55．9 W。本文对低温制冷机蓄冷材料选择具有一定的参考价值。     

一维光子晶体缺陷模激光器的放大特性

光子晶体中引入缺陷后将形成缺陷模,这些缺陷模在增益介质中将被放大形成激光。基于麦克斯韦方程和速率方程相结合的模型,用时域有限差分法(FDTD)计算和分析了一维单缺陷光子晶体激光器中缺陷模的空间分布和频谱特性,以及这些缺陷模的放大特性,主要研究了缺陷层的厚度、晶体层数对缺陷模放大特性的影响。模拟结果显示,类似于传统激光腔的腔模,这些缺陷模能够被放大,形成激光。调整缺陷层的厚度、晶体层数等结构参量,将改变缺陷模的谐振,激射频率以及空间分布,这将直接影响激射阈值和饱和特性。增加晶体的层数,激光器的阈值将降低,饱和值将增加,但晶体层数增加到一定限度时,这种增减趋势变弱。模拟结果证明了有效层数的存在。     

Fission Barrier for ^240Pu in the Quadrupole Constrained Relativistic Mean Field Approach

The fission barrier for ^240pu is investigated beyond the second saddle point in the potentiM energy surface by the constrained relativistic mean field method with the newly proposed parameter set PK1. The microscopic correction for the centre-of-mass motion is essentiM to provide the correct potential energy surface. The shell effects that stabilize the nuclei against the fission is also investigated by the Strutinsky method. The shapes for the ground state, fission isomer and saddle-points, etc, are studied in detail.